Two cylinder termogravitational columns have been used to study the behaviour of several liquid binary mixtures under the action of a horizontal temperature gradient. It has been found that the relation between the solubility parameters, the molecular weights and the normal boiling points of the components gives no indication as to the component concentrating in each extremity of the column, at steady state. For all but two of the liquid pairs studied the component with the higher density concentrates at the bottom of the column. Some separation data on twenty-six binary systems are presented.